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MIT OpenCourseWare

Liquid-Liquid Spinodal Decomposition and Chemical Reaction Systems in Advanced Thermodynamics - Lecture 17

MIT OpenCourseWare via YouTube

Overview

Learn about liquid-liquid spinodal decomposition and chemical reaction systems in this advanced thermodynamics lecture from MIT's Spring 2024 course. Explore Henry's law, Lennard-Jones binary mixture models, and stability conditions for non-ideal mixtures. Examine the fascinating "Ouzo Effect" and understand the principles behind liquid-vapor equilibria. Delve into energy and entropy balances for both open and closed systems with chemical reactions, while comparing bond strengths to van der Waals forces. Master key concepts including reaction coordinates, stoichiometry, and enthalpy of formation through detailed explanations and practical examples. The instructor recommends viewing at 1.5x speed for optimal learning efficiency in this comprehensive exploration of advanced thermodynamic principles.

Syllabus

- Introduction
- Liquid-Vapor Equilibria for Non-Ideal Mixtures
- Henry's Law for Dilute Non-Ideal Solutions
- Careful in Taking Derivatives!
- Stability Conditions for a Binary Mixtures
- Non-Ideal Mixture Behavior: Complete Miscibility
- Non-Ideal Mixture Behavior: Partial Miscibility
- Spinodal Decomposition
- The “Ouzo Effect”
- Introduction to Systems with Chemical Reactions
- Energy and Entropy Balances with Chemical Reaction
- Notation and Stoichiometry: Reaction Coordinates
- Proportionality Relations; Properties of Reaction
- Enthalpy of Formation Illustrated on a H-S Diagram
- Van der Waals Forces versus Covalent Bonds

Taught by

MIT OpenCourseWare

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