Class Central is learner-supported. When you buy through links on our site, we may earn an affiliate commission.

XuetangX

Thermodynamics of materials & phase transformations

Northwestern Polytechnical University via XuetangX

Overview

Studying material problems using the principles and methods of thermodynamics and statistical thermodynamics is called material thermodynamics. It forms the foundation of material science with dynamics, crystallography, and solid physics and solid chemistry. Material engineering includes the design, manufacturing, molding, and testing of materials. It is a comprehensive discipline that applies the principles of material science to material design and processing. Materials science and engineering have become a whole. The application of thermodynamics in this field has increasingly shown its positive role in developing the variety and improving the quality of materials. Applying the principles of material thermodynamics can clarify and predict phase diagrams, phase transitions, and other physical phenomena of materials.

The course "Thermodynamics; of materials & phase transformations" is the core basic course for undergraduate students majoring in materials at Northwestern Polytechnic University. The main task of this course is to cultivate students' ability to apply basic thermodynamic principles to solve specific problems in material research and explain thermodynamics and phase transition phenomena in material science. The main content of the course includes: the three laws of thermodynamics, solution thermodynamics, phase diagram thermodynamics, and so on.

Through this course, you need to master the concept, applicable conditions, and significance of thermodynamic laws. It is necessary to understand how to apply thermodynamic laws (i.e., thermodynamic functions) in the field of materials to reveal the laws of material science, master the concepts, functions, and applications of thermodynamic laws, and be able to use them to solve specific problems in material research and explain thermodynamic phenomena in material science research. Understand the enthalpy, entropy, free energy, partial molar volume, and activity of thermodynamic parameters in specific materials. It is necessary to understand important functions in thermodynamics, especially the Maxwell relationship, as well as the concepts and differences between ideal solutions, dilute solutions, and regular solutions. Students need to be familiar with the concept of Gibbs free energy, the Clausius Clapeyron equation, and be able to accurately analyze the phase diagrams of pure substances. You need to understand the principles and concepts of thermodynamics, laws, binary phase diagrams and their applications, phase diagram thermodynamics, phase change thermodynamics, and solution thermodynamics, and can solve some problems in material research.

 

Syllabus

  • 0.Introductions
    • 1.Introduction and definition of terms
      • 1.1 System & Surroundings
      • 1.2 State
      • 1.3 Phase diagram
    • 2.The First Law of thermodynamics
      • 2.1 The formula
      • 2.2 Process & Heat capacity
      • 2.3 Cp-Cv
      • 2.4 Reversible processes
      • 2.5 Qualitative example problems
    • 3.The Second Law of thermodynamics
      • 3.1 Irreversibility and Entropy
      • 3.2 Irreversible and reversible processes
      • 3.3 Heat engines
      • 3.4 Introduction of entropy from heat engines
      • 3.5 The First Law + The Second Law
    • 4.The statistical interpretation of entropy
      • 4.1 Mixed-up-ness & microstate
      • 4.2 The microcanonical approach-Thermal entropy
      • 4.3 The microcanonical approach-Configurational entropy
      • 4.4 The Boltzmann Distribution
      • 4.5 The Boltzmann equation
    • 5.Fundamental Equations and Their Relationships
      • 5.1 Thermodynamic functions
      • 5.2 The chemical potential
      • 5.3 Maxwell’s equations and their application
      • 5.4 Gibbs-Helmholtz equation
    • 6.Heat capacity, enthalpy, entropy, and the third law of thermodynamics
      • 6.1 Enthalpy as a function of temperature and composition
      • 6.2 Entropy and the third law of thermodynamics
      • 6.3 Experimental verification of the third law
      • 6.4 The influence of pressure on enthalpy and entropy
    • 7.Phase equilibrium in a one-component system
      • 7.1 The variation of Gibbs free energy with temperature
      • 7.2 The Gibbs free energy as a function of temperature and pressure
      • 7.3 Vapor phase and condensed phase Equilibria
      • 7.4 Solid-Solid Equilibria
    • 8.The Behavior of Gases
      • 8.1 Mixtures of Ideal Gases
      • 8.2 Thermodynamic Properties of Ideal Gases
      • 8.3 Deviation from Ideality for Real Gases
      • 8.4 The Van Der Waals Fluid P~V curve
      • 8.5 The Van Der Waals Fluid G~P curve
    • 9.The Behavior of Solutions
      • 9.1 Raoult’s Law and Henry’s Law
      • 9.2 Thermodynamic Activity
      • 9.3 The Gibbs-Duhem Equation
      • 9.4 The Gibbs Free Energy of Formation of a Solution
      • 9.5 The Properties of Ideal Solutions
      • 9.6 Non-Ideal Solutions
      • 9.7 Apply Gibbs-Duhem relation to determine Activity
      • 9.8 Regular Solutions
    • 10.Gibbs Free energy Composition and Phase Diagrams of Binary Systems
      • 10.1 Gibbs Free Energy and Thermodynamic Activity
      • 10.2 Regular Solution Model
      • 10.3 The Eutectic and Eutectoid Phase Diagrams
      • 10.4 The Peritectic and Peritectoid Phase Diagrams
      • 10.5 The Gibbs Free Energy of Formation of Regular Solutions
    • 11.Reactions Involving Gases
      • 11.1 Reaction Equilibrium in a Gas Mixture
      • 11.2 The Effect of Temperature on the Equilibrium Constant
      • 11.3 The Effect of Pressure on the Equilibrium Constant
      • 11.4 Reaction Equilibrium as a Compromise between Enthalpy and Entropy
    • 12.Reactions Involving Pure Condensed Phases and a Gaseous Phase
      • 12.1 Reaction Equilibrium
      • 12.2 The Variation of the Standard Gibbs Free Energy Change with Temperature
      • 12.3 Ellingham Diagrams
      • 12.4 The Effect of Phase Transformation
    • 13.Reactions Equilibria in Systems Containing Components in Condensed Solution
      • 13.1 The Criteria For Reaction Equilibrium
      • 13.2 Alternative Standard States
      • 13.3 The Gibbs Equilibrium Phase Rule
    • Final exam

      Taught by

      Wang Haifeng, Zhou Qing, Wang Xianzong, Hua Ke, and He Yixuan

      Tags

      Reviews

      Start your review of Thermodynamics of materials & phase transformations

      Never Stop Learning.

      Get personalized course recommendations, track subjects and courses with reminders, and more.

      Someone learning on their laptop while sitting on the floor.