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MIT OpenCourseWare

Stratification in Gas and Liquid Mixtures and Liquid-Vapor Spinodal Decomposition - Lecture 15

MIT OpenCourseWare via YouTube

Overview

Explore advanced thermodynamics concepts in this comprehensive lecture focusing on stratification phenomena in gas and liquid mixtures under various field conditions. Learn about mixing and separation processes, including detailed analysis of ideal gas mixing entropy and minimum work requirements for mixture separation. Examine stratification effects in gravitational fields, with practical applications to atmospheric oxygen and CO2 concentration variations by elevation, and ocean-atmosphere equilibrium. Delve into centrifugal separation techniques, including uranium enrichment applications, and investigate charge stratification in electric fields. Master liquid-vapor equilibria concepts in pure substances through Lennard-Jones potential and Van der Waals models, understanding metastable states and spinodal decomposition. Conclude with practical applications in Wilson Cloud Chamber and Glaser Bubble Chamber technologies. Set playback speed to 1.5x for optimal learning efficiency in this MIT OpenCourseWare advanced thermodynamics lecture.

Syllabus

- Introduction
- Mixing and Separation. Stratification
- Review: Mixing of Ideal Gases; Entropy of Mixing
- Review: Adiabatic Availability of Mixing
- Minimum Work of Complete Mixture Separation
- Illustration on an Energy vs Entropy Diagram
- Ideal Separation Using Semipermeable Membranes
- Stratification of Mixtures in Gravity Field
- Stratification in the Atmosphere
- Mutual Equilibrium Between Ocean and Atmosphere
- Stratification of Mixtures in a Centrifuge
- Gas Centrifuges for Uranium Enrichment
- Stratification of Charges in an Electric Field
- Liquid-Vapor Equilibria in Pure Substances
- Review: Lennard-Jones Potential
- Lennard-Jones Pure Substance “Lennardjonesium”
- Van der Waals Non-Ideal Behavior Model
- Van der Waals Metastable and Unstable States
- Wilson Cloud Chamber and Glaser Bubble Chamber
- Liquid-Vapor Spinodal Decomposition

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MIT OpenCourseWare

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