Organic Photochemistry and Pericyclic Reactions

Overview

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Instructor: Prof. N. D. Pradeep Singh, Department of Chemistry, IIT Kharagpur.

The course will involve a discussion of molecular organic photochemistry and pericyclic reactions. Initially, we will study in brief the fundamental principles of photochemistry. In the following lectures, we will discuss the primary photochemical reactions of n,π*states. In the second half of our course, we will be focusing on the primary photochemical reactions of π,π*states where we will discuss in detail the pericyclic reactions. We will end our course by studying some important applications of photochemistry.

Syllabus

Mod-01 Lec-01 Introduction to Organic Photochemistry.
Mod-01 Lec-02 Introduction to Organic Photochemistry (Contd.).
Mod-01 Lec-03 Reactivity of n-pi*.
Mod-01 Lec-04 α - cleavage - I.
Mod-01 Lec-05 α - cleavage - II.
Mod-01 Lec-06 α - cleavage - III.
Mod-01 Lec-07 β - cleavage.
Mod-01 Lec-08 Intramolecular Hydrogen Abstraction - I.
Mod-01 Lec-09 Intramolecular Hydrogen Abstraction - II.
Mod-01 Lec-10 Intramolecular Hydrogen Abstraction - III.
Mod-01 Lec-11 Intramolecular Hydrogen Abstraction.
Mod-01 Lec-12 Addition to Π - System.
Mod-01 Lec-13 Intramolecular Paterno-Buchi Reaction.
Mod-01 Lec-14 Energy of Electron Transfer Reaction.
Mod-01 Lec-15 Reactivity of Π - Π*.
Mod-01 Lec-16 Addition Reaction of Π - Π *.
Mod-01 Lec-17 Addition Reaction of Π - Π * (Contd.).
Mod-01 Lec-18 Di-Pi Methane Rearrangement.
Mod-01 Lec-19 Photochemistry of Cyclohexanone.
Mod-01 Lec-20 Singlet Oxygen Chemistry.
Mod-01 Lec-21 Carbenes and Nitrenes.
Mod-01 Lec-22 Remote Functionalisation.
Mod-01 Lec-23 Introduction to Pericyclic Reaction.
Mod-01 Lec-24 Sigmatropic Reactions - I.
Mod-01 Lec-25 Sigmatropic Reactions - II.
Mod-01 Lec-26 Sigmatropic Reactions - III.
Mod-01 Lec-27 Cycloaddition Reactions - I.
Mod-01 Lec-28 Cycloaddition Reactions - II.
Mod-01 Lec-29 Cycloaddition - Diels-Alder Reactions.
Mod-01 Lec-30 Cycloaddition - Diels-Alder Reactions (Contd.).
Mod-01 Lec-31 Cycloaddition - Ene Reactions.
Mod-01 Lec-32 1,3 Dipolar Cycloaddition - I.
Mod-01 Lec-33 1,3 Dipolar Cycloaddition - II.
Mod-01 Lec-34 Electrocyclic Reaction - I.
Mod-01 Lec-35 Electrocyclic Reaction - II.
Mod-01 Lec-36 Practice Problems in Pericyclic Reaction - I.
Mod-01 Lec-37 Practice Problems in Pericyclic Reaction - II.
Mod-01 Lec-38 Practice Problems in Pericyclic Reaction - III.
Mod-01 Lec-39 Chelotropic Reaction.
Mod-01 Lec-40 Application of Photochemistry.