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Instructor: Prof. D. R. Mal, Department of Chemistry, IIT Kharagpur.
This course talks about heterocyclic chemistry. Topics covered in this course include Definition of heteroatom and alkaloids, Nomenclature of heterocyclic compounds, Effect of heteroatoms on organic reactions: comparison with carbogenic compounds, Aromatic heterocyclic chemistry, Non-aromatic heterocyclic chemistry, and Miscellaneous group.
Mod-01 Lec-01 Definition and Scope.
Mod-02 Lec-02 Single - Step Methods for IVPs.
Mod-03 Lec-03 Systematic Nomenclature.
Mod-04 Lec-04 Nomenclature (Contd.) and Important Names.
Mod-05 Lec-05 Overview of Structure Determination in Heterocyclic Chemistry.
Mod-06 Lec-06 15N NMR in Heterocyclic Chemistry.
Mod-07 Lec-07 Effects of Ring Nitrogen - A.
Mod-08 Lec-08 Effects of Ring Nitrogen - B.
Mod-09 Lec-09 Effects of Ring Nitrogen - C.
Mod-10 Lec-10 Oxidation in Heterocyclic Chemistry.
Mod-10 Lec-11 Oxidation in Heterocyclic Chemistry (Contd.).
Mod-11 Lec-12 Reduction in Heterocyclic Chemistry.
Mod-12 Lec-13 Radicals in Heterocylic Chemistry - I.
Mod-13 Lec-14 Radicals in Heterocylic Chemistry - II.
Mod-14 Lec-15 Lithiation for 5-membered heterocycles.
Mod-14 Lec-16 Lithiation for 5-membered heterocycles (Contd.).
Mod-15 Lec-17 Lithiation of 6-membered heterocycle and non-aromatic heterocycles.
Mod-16 Lec-18 Magnetiation and Zincation in Heterocyclic Chemistry.
Mod-17 Lec-19 Transition metal catalyzed cross coupling.
Mod-17 Lec-20 Transition metal catalyzed cross coupling (Contd.).
Mod-18 Lec-21 Dehydrogenative (Oxidative) cross coupling.
Mod-19 Lec-22 Tert-amino effect in heterocycle synthesis.
Mod-20 Lec-23 [4 plus 2] cycloaddition in heterocyclic chemistry.
Mod-20 Lec-24 [4 plus 2] cycloaddition in heterocyclic chemistry (Contd.).
Mod-21 Lec-25 [3 plus 2] Cycloaddition in heterocyclic chemistry.
Mod-22 Lec-26 Cycloaddition : Revisited.
Mod-23 Lec-27 [4 plus 3] Cycloaddition.
Mod-24 Lec-28 [5 plus 2] Cycloaddition.
Mod-25 Lec-29 [2 plus 2 plus 2] Cycloaddition.
Mod-26 Lec-30 Pyrrole Synthesis - I.
Mod-27 Lec-31 Pyrrole Synthesis - II.
Mod-28 Lec-32 Indole Synthesis - I.
Mod-29 Lec-33 Indole Synthesis - II.
Mod-30 Lec-34 Furan Synthesis.
Mod-31 Lec-35 Thiophene Synthesis.
Mod-32 Lec-36 Oxazole, Imidazole and Thiazole Synthesis.
Mod-33 Lec-37 Pyridine Synthesis.
Mod-34 Lec-38 Synthesis of Quinolines and Isoquinolines.
Mod-35 Lec-39 Bycyclic Polyheteroatomic Heterocycles.
Mod-36 Lec-40 Heterocyclic Rearrangements.
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