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CHIRAL LEWIS ACIDS & STEREOSELECTIVE POLYMERIZATION
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Classroom Contents
Stereoselective Cationic Polymerization of Prochiral Monomers
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- 1 Intro
- 2 STEREOCHEMISTRY LEADS TO EMERGENT PROPERTIES
- 3 CANONICAL METHODS TO CONTROL POLYMER STEREOCHEMISTRY
- 4 MECHANISM FOR STEREOINDUCTION IN OLEFIN POLYMERIZATION
- 5 A NEW APPROACH: STEREOSELECTIVE CATIONIC POLYMERIZATION
- 6 USING CHIRAL COUNTERIONS TO CONTROL STEREOCHEMISTRY
- 7 PREMIER METHOD FOR STEREOCONTROLLED VINYL ETHER POLYMERIZATION
- 8 CHIRAL LEWIS ACIDS & STEREOSELECTIVE POLYMERIZATION
- 9 CATALYST SUBSTITUTION MATTERS
- 10 OPTIMIZATION OF REACTION CONDITIONS IMPROVES ISOTACTICITY
- 11 A GENERAL METHOD FOR THE SYNTHESIS OF ISOTACTIC PVES
- 12 CHIRAL COUNTER-ION APPROACH ENABLES CATALYST CONTROL
- 13 PROPOSED MECHANISM OF STEREOSELECTIVE CATIONIC POLYMERIZATION
- 14 KINETICS REVEAL LIGAND EFFECTS
- 15 ARRHENIUS ANALYSIS QUANTITATES KINETICS OF POLYMERIZATION
- 16 CATALYST SOLUTION STRUCTURE IS A MYSTERY
- 17 COMPUTATIONAL ANALYSIS REVEALS A PROPOSED STRUCTURE
- 18 STEREOCONTROL IMPARTS EMERGENT MECHANICAL PROPERTIES
- 19 IMPROVEMENTS IN CATALYST DESIGN TO FACILITATE NEW REACTIVITY
- 20 CHAIN TRANSFER AGENTS ENABLE LOW CATALYST LOADING
- 21 IS CHIRAL COUNTERION CATALYSIS A GENERAL APPROACH?
- 22 CONTROLLING POLYMER CONFIGURATION TO CONFORMATION
- 23 IMPROVING ISOTACTICITY THROUGH LIGAND MODIFICATION
- 24 INVESTIGATING THE SOURCE OF HIGH STEREOSELECTIVITY
- 25 PROPOSED STEREODETERMINING STEPS
- 26 FIRST MONOMER PROPAGATION DETERMINES HELICITY
