Stereoselective Cationic Polymerization of Prochiral Monomers

Stereoselective Cationic Polymerization of Prochiral Monomers

NSF Center for Integrated Catalysis via YouTube Direct link

PREMIER METHOD FOR STEREOCONTROLLED VINYL ETHER POLYMERIZATION

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7 of 26

PREMIER METHOD FOR STEREOCONTROLLED VINYL ETHER POLYMERIZATION

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Classroom Contents

Stereoselective Cationic Polymerization of Prochiral Monomers

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  1. 1 Intro
  2. 2 STEREOCHEMISTRY LEADS TO EMERGENT PROPERTIES
  3. 3 CANONICAL METHODS TO CONTROL POLYMER STEREOCHEMISTRY
  4. 4 MECHANISM FOR STEREOINDUCTION IN OLEFIN POLYMERIZATION
  5. 5 A NEW APPROACH: STEREOSELECTIVE CATIONIC POLYMERIZATION
  6. 6 USING CHIRAL COUNTERIONS TO CONTROL STEREOCHEMISTRY
  7. 7 PREMIER METHOD FOR STEREOCONTROLLED VINYL ETHER POLYMERIZATION
  8. 8 CHIRAL LEWIS ACIDS & STEREOSELECTIVE POLYMERIZATION
  9. 9 CATALYST SUBSTITUTION MATTERS
  10. 10 OPTIMIZATION OF REACTION CONDITIONS IMPROVES ISOTACTICITY
  11. 11 A GENERAL METHOD FOR THE SYNTHESIS OF ISOTACTIC PVES
  12. 12 CHIRAL COUNTER-ION APPROACH ENABLES CATALYST CONTROL
  13. 13 PROPOSED MECHANISM OF STEREOSELECTIVE CATIONIC POLYMERIZATION
  14. 14 KINETICS REVEAL LIGAND EFFECTS
  15. 15 ARRHENIUS ANALYSIS QUANTITATES KINETICS OF POLYMERIZATION
  16. 16 CATALYST SOLUTION STRUCTURE IS A MYSTERY
  17. 17 COMPUTATIONAL ANALYSIS REVEALS A PROPOSED STRUCTURE
  18. 18 STEREOCONTROL IMPARTS EMERGENT MECHANICAL PROPERTIES
  19. 19 IMPROVEMENTS IN CATALYST DESIGN TO FACILITATE NEW REACTIVITY
  20. 20 CHAIN TRANSFER AGENTS ENABLE LOW CATALYST LOADING
  21. 21 IS CHIRAL COUNTERION CATALYSIS A GENERAL APPROACH?
  22. 22 CONTROLLING POLYMER CONFIGURATION TO CONFORMATION
  23. 23 IMPROVING ISOTACTICITY THROUGH LIGAND MODIFICATION
  24. 24 INVESTIGATING THE SOURCE OF HIGH STEREOSELECTIVITY
  25. 25 PROPOSED STEREODETERMINING STEPS
  26. 26 FIRST MONOMER PROPAGATION DETERMINES HELICITY

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