COURSE OUTLINE: In any chemical process, often one encounter interaction between phases where the transfer of species takes place from one phase to other. There exists several situations of vapor-liquid, liquid-liquid, vapor-liquid-liquid, solid-liquid equilibria in chemical engineering processes. Often these situations are dealt with assumption of ideal behavior and binary systems but in reality non-ideality and multicomponent mixtures exists and accordingly one has to deal with such situations. This course offers step-by-step understanding of required thermodynamic properties to handle such equilibrium cases and explore possible ways of solving problems associated with non-ideality in VLE, LLE, VLLE and SLE for multicomponent mixtures.
Overview
Syllabus
Advanced Thermodynamics [Introduction Video].
Lec 1 : Introduction of Phase Equilibrium.
Lec 2 : Classical Thermodynamics of Phase Equilibria.
Lec 3 : Classical Thermodynamics of Phase Equilibria – 2.
Lec 4: Thermodynamic Properties from Volumetric Data.
Lec 5: Fugacity from Volumetric Data - 1.
Lec 6: Fugacity from Volumetric Data – 2.
Lec 7: Intermolecular Forces and Non-Ideal Behaviour.
Lec 8: Intermolecular Forces-Potential Energy Functions.
Lec 9: Molecular Theory of Corresponding States.
Lec 10: Molecular Theory of Corresponding States – 2.
Lec 11: Intermolecular Potential and EoS.
Lec 12: Virial Coefficients from Potential Functions.
Lec 13: Virial Coefficients from Corresponding States Theory.
Lec 14: Fugacities in Gaseous Mixtures.
Lec 15: Fugacities in Gaseous Mixtures - 2.
Lec 16: Fugacities in Gaseous Mixtures - 3.
Lec 17: Liquid Mixtures and Excess Functions.
Lec 18: Excess Functions and Activity Coefficients.
Lec 19: Activity Coefficients and Thermodynamic Consistency.
Lec 20: Models for Excess Gibbs Energy.
Lec 21: Models for Excess Gibbs Energy - 2.
Lec 22: Models for Excess Gibbs Energy - 3.
Lec 23: Vapour - Liquid Equilibrium.
Lec 24: Vapour - Liquid Equilibrium - 2.
Lec 25: Vapour - Liquid Equilibrium - 3.
Lec 26: Liquid - Liquid Equilibrium.
Lec 27: Liquid - Liquid Equilibrium - 2.
Lec 28: Vapour - Liquid - Liquid Equilibrium.
Lec 29: Vapour - Liquid - Liquid Equilibrium - 2.
Lec 30: Solid - Liquid Equilibrium.
Lec 31: Solid - Liquid Equilibrium - 2.
Taught by
NPTEL IIT Guwahati
