Class Central is learner-supported. When you buy through links on our site, we may earn an affiliate commission.

Yale University

Higher-Order Effects, Dynamics, and the NMR Time Scale - Lecture 24

Yale University via YouTube

Overview

Explore advanced concepts in organic chemistry through this 51-minute lecture from Yale University's Freshman Organic Chemistry II course. Delve into the intricacies of spin-spin splitting, higher-order effects, and the NMR time scale. Examine how hybridization affects C-13 splitting and understand complex multiplets resulting from nuclei with similar chemical shifts. Learn to measure rapid changes in molecular structure using chemical shift and spin-spin splitting averaging. Apply your knowledge to predict NMR spectra for compounds with diastereotopic groups. Discover the technique of proton decoupling in NMR spectroscopy. The lecture concludes with an introduction to electrophile activation in Friedel-Crafts reactions, providing a comprehensive overview of advanced organic chemistry principles.

Syllabus

- Chapter 1. Hybridization and Splitting by C-13
.
- Chapter 2. Higher-Order Effects: Why Methane Gives a Singlet
.
- Chapter 3. Averaging and the NMR Time Scale
.
- Chapter 4. Predicting an NMR Spectrum
.
- Chapter 5. Electrophile Activation: Friedel and Crafts
.

Taught by

YaleCourses

Reviews

Start your review of Higher-Order Effects, Dynamics, and the NMR Time Scale - Lecture 24

Never Stop Learning.

Get personalized course recommendations, track subjects and courses with reminders, and more.

Someone learning on their laptop while sitting on the floor.