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Indian Institute of Technology, Kharagpur

Adsorption Science and Technology: Fundamentals and Applications

Indian Institute of Technology, Kharagpur and NPTEL via Swayam

Overview

ABOUT THE COURSE: The course is designed focusing on the adsorption fundamentals and the application, both at the introductory and advanced level. Adsorption technology is an important separation technology that has wide spread applications from waste water treatment to chromatography, ion exchange, gas separation based on pressure swing adsorption (for e.g. in medical oxygen concentrators), and other surface based transfer processes. The course is related to the scientific principles involved in various industry sectors including petroleum refining, oil and gas, petrochemicals, polymers, catalyst, gas separation, energy, process design, water purification and treatment, waste treatment, etc.In the recent emphasis on environmental sustainability and climate change, adsorption is important for carbon capture technologies, waste separation and recovery of value added products from waste streams.INTENDED AUDIENCE: Pursuing UG / PG / PhD degree courses in Chemical engineering, biotechnology, Chemistry, Pharmaceutical engineering, Mechanical engineering and agricultural engineering.Industry professionals involved in the sectors of petroleum refining, oil and gas, petrochemicals, polymers, catalyst, gas separation, energy, process design, water purification and treatment, waste treatment, etc.PREREQUISITES: Pursuing UG / PG / PhD degree courses in Chemical engineering, biotechnology, Chemistry, Pharmaceutical engineering, Mechanical engineering and agricultural engineering.INDUSTRY SUPPORT: Industry sectors – petroleum refining, petrochemicals, polymers, catalyst, gas separation, energy, process design, water purification and treatment, waste treatment, etc.

Syllabus

Week 1:
  • background of adsorption with real life examples
  • types and properties of adsorbents
  • key features of adsorption, thermodynamic background
  • concept of adsorption isotherm
  • Langmuir isotherm
Week 2:
  • langmuir multicomponent and other important isotherms
  • gas and liquid adsorption
  • equilibrium modelling ‐ I
  • equilibrium modelling ‐ II
  • adsorption kinetics
Week 3:
  • BET analysis ‐ equipment
  • Gas sorption
  • surface area calculations
  • pore size analysis
  • Limitations
Week 4:
  • adsorption diffusion models
  • linear driving force model
  • film diffusion
  • intraparticle adsorption diffusion model
  • multiscale model of batch adsorption
Week 5:
  • fixed bed adsorption, concept of breakthrough
  • mass transfer zone modelling
  • semi‐empirical bed models
  • (thomas, clark, yoon‐nelson, etc.)
  • BDST model
  • first principle model
  • (combined hydrodynamics + mass transfer + adsorption)
Week 6:
  • multi‐scale bed model ‐ I
  • multi‐scale bed model ‐ II
  • pressure swing adsorption (PSA) ‐ introduction
  • modelling dual column PSA
  • design of medical grade oxygenator
Week 7:
  • introduction to chromatography
  • principles
  • column chromatography
  • mass transfer models‐I
  • mass transfer models‐II
Week 8:
  • ion exchange‐principles
  • ion exchange adsorbents
  • regeneration
  • design of ion exchange column
  • mass transport modelling

Taught by

Prof. Sourav Mondal

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