Paired Calcium and Clumped Isotopes, Tools to Probe Changing Diagenetic Systems

Paired Calcium and Clumped Isotopes, Tools to Probe Changing Diagenetic Systems

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Shallow carbonate as a chemical archive? . Complicated - margin carbonate archives give conflicting, often contradictory geochemical signals to less complicated pelagic archives.

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Shallow carbonate as a chemical archive? . Complicated - margin carbonate archives give conflicting, often contradictory geochemical signals to less complicated pelagic archives.

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Paired Calcium and Clumped Isotopes, Tools to Probe Changing Diagenetic Systems

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  1. 1 Intro
  2. 2 Talk layout: • Depositional setting: The Bahamian Margin Fluid-carbonate reactive exchange and its effects on geochemical records
  3. 3 Depositional Setting: Bahamian Margin • Platform margin sediment consists of re-deposited shallow marine sediments and pelagic material
  4. 4 Depositional Setting: Site 1003 ODP Site 1003 - Sampled on ODP Leg 166 in 1997
  5. 5 Shallow carbonate as a chemical archive? . Complicated - margin carbonate archives give conflicting, often contradictory geochemical signals to less complicated pelagic archives.
  6. 6 Fluid-sediment reactive exchange
  7. 7 The problem • Because sediments are progressively buried over time, recrystallizing sediments exchange with porefluids with different degrees of rock-buffering.
  8. 8 How to constrain reaction rate
  9. 9 Clumped isotopes: a one-slide primer
  10. 10 How to constrain recrystallization rate
  11. 11 Modeling variable reaction rate A single function for early and late diagenesis
  12. 12 How fast do fluids flow into margin?
  13. 13 A dataset for 84Ca on the Bahamian margin
  14. 14 Solving for advection rate
  15. 15 Fluid flow rates into the Bahamian margin
  16. 16 Correcting a 813C record for diagenesis
  17. 17 What can we do with these advection rates?
  18. 18 Carbon Isotopes on the platform margin
  19. 19 A consistent story?
  20. 20 Dissecting The problem • Diffusion rates are well-constrained experimentally
  21. 21 Summarizing the process . Carbonate and fluid geochemistry can be modeled over time. . This requires an understanding of reactive and advective behavior
  22. 22 Thank you for listening Referencing of work
  23. 23 IAS

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