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Lecture 18 (4 of 8) - Intermediate Max and Rate Det Step
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Physical Chemistry - Thermodynamics, Statics, and Kinetics
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- 1 Lecture 1 (1 of 2) - Course Introduction
- 2 Lecture 1 (2 of 2) - Concentrations
- 3 Lecture 2 (1 of 6) - Properties of Gases Introduction
- 4 Lecture 2 (2 of 6) - The Ideal Gas Law
- 5 Lecture 2 (3 of 6) - Ideal Gases (cont.)
- 6 Lecture 2 (4 of 6) - Dalton's Law
- 7 Lecture 2 (5 of 6) - Real Gases
- 8 Lecture 2 (6 of 6) - Gas Law Examples
- 9 Lecture 3 (1 of 4) - Internal Energy
- 10 Lecture 3 (2 of 4) - Expansion Work
- 11 Lecture 3 (3 of 4) - Heat
- 12 Lecture 3 (4 of 4) - First Law of Thermodynamics Examples
- 13 Lecture 4 (1 of 6) - Enthalpy Introduction
- 14 Lecture 4 (2 of 6) - Difference Between H and U
- 15 Lecture 4 (3 of 6) - Heat Capacity at Constant Pressure
- 16 Lecture 4 (4 of 6) - Hess' Law
- 17 Lecture 4 (5 of 6) - Hess' Law Applications
- 18 Lecture 4 (6 of 6) - Kirchhoff's Law
- 19 Lecture 5 (1 of 5) - Adiabatic Behaviour
- 20 Lecture 5 (2 of 5) - Adiabatic Expansion Work
- 21 Lecture 5 (3 of 5) - Heat Engines
- 22 Lecture 5 (4 of 5) - Total Carnot Work
- 23 Lecture 5 (5 of 5) - Heat Engine Efficiency
- 24 Lecture 6 (1 of 4) - Microstates and Macrostates
- 25 Lecture 6 (2 of 4) - Partition Functions
- 26 Lecture 6 (3 of 4) - Partition Functions Examples
- 27 Lecture 6 (4 of 4) - Calculating U from Partition Functions
- 28 Lecture 7 (1 of 4) - Entropy
- 29 Lecture 7 (2 of 4) - Change in Entropy Examples
- 30 Lecture 7 (3 of 4) - Residual Entropies and the Third Law
- 31 Lecture 7 (4 of 4) - Absolute Entropies and Spontaneity
- 32 Lecture 8 (1 of 7) - Free Energies
- 33 Lecture 8 (2 of 7) - The Gibbs Free Energy
- 34 Lecture 8 (3 of 7) - Phase Diagrams
- 35 Lecture 8 (4 of 7) - Building Phase Diagrams
- 36 Lecture 8 (5 of 7) - The Clapeyron Equation
- 37 Lecture 8 (6 of 7) - The Clapeyron Equation Example
- 38 Lecture 8 (7 of 7) - The Clausius Clapeyron Equation
- 39 Lecture 9 (1 of 5) - Chemical Potential
- 40 Lecture 9 (2 of 5) - The Mixing of Gases
- 41 Lecture 9 (3 of 5) - Raoult's Law
- 42 Lecture 9 (4 of 5) - Real Solutions
- 43 Lecture 9 (5 of 5) - Dilute Solutions
- 44 Lecture 10 (1 of 4) - Colligative Properties
- 45 Lecture 10 (2 of 4) - Fractional Distillation
- 46 Lecture 10 (3 of 4) - Freezing Point Depression
- 47 Lecture 10 (4 of 4) - Osmosis
- 48 Lecture 11 (1 of 5) - Chemical Potential and Equilibrium
- 49 Lecture 11 (2 of 5) - The Equilibrium Constant
- 50 Lecture 11 (3 of 5) - Equilibrium Concentrations
- 51 Lecture 11 (4 of 5) - Le Chatelier and Temperature
- 52 Lecture 11 (5 of 5) - Le Chaterler and Pressure
- 53 Lecture 12 (1 of 5) - Ions in Solution
- 54 Lecture 12 (2 of 5) - Debye-Hückel Law
- 55 Lecture 12 (3 of 5) - Salting In and Salting Out
- 56 Lecture 12 (4 of 5) - Salting In Example
- 57 Lecture 12 (5 of 5) - Salting Out Example
- 58 Lecture 13 (1 of 4) - Acid Equilibrium Review
- 59 Lecture 13 (2 of 4) - Real Acid Equilibrium
- 60 Lecture 13 (3 of 4) - The pH of Real Acid Solutions
- 61 Lecture 13 (4 of 4) - Buffers
- 62 Lecture 15 (1 of 5) - Rate Law Expressions
- 63 Lecture 15 (2 of 5) - 2nd Order Type 2 Integrated Rate Law
- 64 Lecture 15 (3 of 5) - 2nd Order Integrated Rate Law (cont.)
- 65 Lecture 15 (4 of 5) - Strategies To Determine Order
- 66 Lecture 15 (5 of 5) - Half Life
- 67 Lecture 16 (1 of 2) - The Arrhenius Equation
- 68 Lecture 16 (2 of 2) - The Arrhenius Equation Examples
- 69 Lecture 17 (1 of 6) - The Approach to Equilibrium
- 70 Lecture 17 (2 of 6) - The Approach to Equilibrium (cont.)
- 71 Lecture 17 (3 of 6) - Link Between K and Rate Constants
- 72 Lecture 17 (4 of 6) - Equilibrium Shift Setup
- 73 Lecture 17 (5 of 6) - Time Constant, Tau
- 74 Lecture 17 (6 of 6) - Quantifying Tau and Concentrations
- 75 Lecture 18 (1 of 8) - Consecutive Chemical Reactions
- 76 Lecture 18 (2 of 8) - Multi-Step Integrated Rate Laws
- 77 Lecture 18 (3 of 8) - Multi-Step Int Rate Laws (cont.)
- 78 Lecture 18 (4 of 8) - Intermediate Max and Rate Det Step
- 79 Lecture 18 (5 of 8) - Preequilibrium Approximation
- 80 Lecture 18 (6 of 8) - Preequilibrium Approximation (cont.)
- 81 Lecture 18 (7 of 8) - Steady State Approximation
- 82 Lecture 18 (8 of 8) - Steady State Approximation (cont.)
- 83 Lecture 19 (1 of 2) - Rate Law Expressions with Catalysts
- 84 Lecture 19 (2 of 2) - Michaelis-Menten Enzyme Rate Law